Enhanced CO2 sorption and selectivity by functionalization of a NbO-type metal-organic framework with polarized benzothiadiazole moieties.

نویسندگان

  • Chengling Song
  • Yabing He
  • Bin Li
  • Yajing Ling
  • Hailong Wang
  • Yunlong Feng
  • Rajamani Krishna
  • Banglin Chen
چکیده

A new NbO-type metal-organic framework ZJNU-40 incorporating highly polarized benzothiadiazole moieties exhibits a high CO2 uptake of 108 cm(3) g(-1) at 296 K and 1 atm, as well as good adsorption selectivities of CO2 over CH4 and N2 at room temperature, which is superior to that of the analogous MOF NOTT-101.

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عنوان ژورنال:
  • Chemical communications

دوره 50 81  شماره 

صفحات  -

تاریخ انتشار 2014